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Emerging roles of liquid metals in carbon neutrality

《能源前沿(英文)》 2022年 第16卷 第3期   页码 393-396 doi: 10.1007/s11708-022-0829-5

Revolutionizing heat transport enhancement with liquid metals: Proposal of a new industry of water-free

Haiyan LI, Jing LIU

《能源前沿(英文)》 2011年 第5卷 第1期   页码 20-42 doi: 10.1007/s11708-011-0139-9

摘要: Water is perhaps the most widely adopted working fluid in conventional industrial heat transport engineering. However, it may no longer be the best option today due to the increasing scarcity of water resources. Furthermore, the wide variations in water supply throughout the year and across different geographic regions also makes it harder to easily access. To address this issue, finding new alternatives to replace water-based technologies is imperative. In this paper, the concept of a water-free heat exchanger is proposed and comprehensively analyzed for the first time. The liquid metal with a low melting point is identified as an ideal fluid that can flexibly be used within a wide range of working temperatures. Some liquid metals and their alloys, which have previously received little attention in thermal management areas, are evaluated. With superior thermal conductivity, electromagnetic field drivability, and extremely low power consumption, liquid metal coolants promise many opportunities for revolutionizing modern heat transport processes: serving as heat transport fluid in industries, administrating thermal management in power and energy systems, and innovating enhanced cooling in electronic or optical devices. Furthermore, comparative analyses are conducted to understand the technical barriers encountered by advanced water-based heat transfer strategies and clarify this new frontier in heat-transport study. In addition, the unique merits of liquid metals that could lead to innovative heat exchanger technologies are evaluated comprehensively. A few promising industrial situations, such as heat recovery, chip cooling, thermoelectricity generation, and military applications, where liquid metals could play irreplaceable roles, were outlined. The technical challenges and scientific issues thus raised are summarized. With their evident ability to meet various critical requirements in modern advanced energy and power industries, liquid metal-enabled technologies are expected to usher a new and global era of water-free heat exchangers.

关键词: heat exchanger     liquid metal     water resource     heat transport enhancement     coolant     thermal management     process engineering     energy crisis     chip cooling    

Unconventional hydrodynamics of hybrid fluid made of liquid metals and aqueous solution under applied

Xu-Dong ZHANG, Yue SUN, Sen CHEN, Jing LIU

《能源前沿(英文)》 2018年 第12卷 第2期   页码 276-296 doi: 10.1007/s11708-018-0545-3

摘要: The hydrodynamic characteristics of hybrid fluid made of liquid metal/aqueous solution are elementary in the design and operation of conductive flow in a variety of newly emerging areas such as chip cooling, soft robot, and biomedical practices. In terms of physical and chemical properties, such as density, thermal conductivity and electrical conductivity, their huge differences between the two fluidic phases remain a big challenge for analyzing the hybrid flow behaviors. Besides, the liquid metal immersed in the solution can move and deform when administrated with non-contact electromagnetic force, or even induced by redox reaction, which is entirely different from the cases of conventional contact force. Owing to its remarkable capability in flow and deformation, liquid metal immersed in the solution is apt to deform on an extremely large scale, resulting in marked changes on its boundary and interface. However, the working mecha- nisms of the movement and deformation of liquid metal lack appropriate models to describe such scientific issues via a set of well-established unified equations. To promote investigations in this important area, the present paper is dedicated to summarizing this unconventional hydrodynamics from experiment, theory, and simulation. Typical experimental phenomena and basic working mechanisms are illustrated, followed by the movement and deformation theories to explain these phenomena. Several representative simulation methods are then proposed to tackle the governing functions of the electrohydrodynamics. Finally, prospects and challenges are raised, offering an insight into the new physics of the hybrid fluid under applied fields.

关键词: liquid metal     hybrid fluid     hydrodynamics     surface tension     applied fields     self-actuation    

Perspective on gallium-based room temperature liquid metal batteries

《能源前沿(英文)》 2022年 第16卷 第1期   页码 23-48 doi: 10.1007/s11708-022-0815-y

摘要: Recent years have witnessed a rapid development of deformable devices and epidermal electronics that are in urgent request for flexible batteries. The intrinsically soft and ductile conductive electrode materials can offer pivotal hints in extending the lifespan of devices under frequent deformation. Featuring inherent liquidity, metallicity, and biocompatibility, Ga-based room-temperature liquid metals (GBRTLMs) are potential candidates to fulfill the requirement of soft batteries. Herein, to illustrate the glamour of liquid components, high-temperature liquid metal batteries (HTLMBs) are briefly summarized from the aspects of principle, application, advantages, and drawbacks. Then, Ga-based liquid metals as main working electrodes in primary and secondary batteries are reviewed in terms of battery configurations, working mechanisms, and functions. Next, Ga-based liquid metals as auxiliary working electrodes in lithium and nonlithium batteries are also discussed, which work as functional self-healing additives to alleviate the degradation and enhance the durability and capacity of the battery system. After that, Ga-based liquid metals as interconnecting electrodes in multi-scenarios including photovoltaics solar cells, generators, and supercapacitors (SCs) are interpreted, respectively. The summary and perspective of Ga-based liquid metals as diverse battery materials are also focused on. Finally, it was suggested that tremendous endeavors are yet to be made in exploring the innovative battery chemistry, inherent reaction mechanism, and multifunctional integration of Ga-based liquid metal battery systems in the coming future.

关键词: liquid metals     soft electrodes     flexible batteries     deformable energy supply devices     epidermal electronics    

Liquid-based high-temperature receiver technologies for next-generation concentrating solar power: A

《能源前沿(英文)》 2023年 第17卷 第1期   页码 16-42 doi: 10.1007/s11708-023-0866-8

摘要: To reduce the levelized cost of energy for concentrating solar power (CSP), the outlet temperature of the solar receiver needs to be higher than 700 °C in the next-generation CSP. Because of extensive engineering application experience, the liquid-based receiver is an attractive receiver technology for the next-generation CSP. This review is focused on four of the most promising liquid-based receivers, including chloride salts, sodium, lead-bismuth, and tin receivers. The challenges of these receivers and corresponding solutions are comprehensively reviewed and classified. It is concluded that combining salt purification and anti-corrosion receiver materials is promising to tackle the corrosion problems of chloride salts at high temperatures. In addition, reducing energy losses of the receiver from sources and during propagation is the most effective way to improve the receiver efficiency. Moreover, resolving the sodium fire risk and material compatibility issues could promote the potential application of liquid-metal receivers. Furthermore, using multiple heat transfer fluids in one system is also a promising way for the next-generation CSP. For example, the liquid sodium is used as the heat transfer fluid while the molten chloride salt is used as the storage medium. In the end, suggestions for future studies are proposed to bridge the research gaps for > 700 °C liquid-based receivers.

关键词: next-generation concentrating solar power     liquid-based solar receiver     molten salt     liquid metals    

ASSESSMENT OF HEAVY METALS IN HYDROCHAR PRODUCED BY HYDROTHERMAL CARBONIZATION OF DAIRY MANURE

《农业科学与工程前沿(英文)》 2023年 第10卷 第3期   页码 437-447 doi: 10.15302/J-FASE-2023507

摘要:

● Content of heavy metals in hydrochar varies considerably, from 50% to 100%.

关键词: heavy metals     dairy manure     hydrochar     hydrothermal carbonization     waste management    

Chemical probe systems for assessing liquidliquid mixing efficiencies of reactors

《化学科学与工程前沿(英文)》 2023年 第17卷 第10期   页码 1323-1335 doi: 10.1007/s11705-022-2275-7

摘要: Liquid–liquid mixing, including homogeneous and heterogeneous mixing, widely exists in the chemical industry. How to quantitatively characterize the mixing performance is important for reactor assessment and development. As a convenient and direct method for mixing characterization, the chemical probe method uses some special test reactions to characterize the mixing results. Here, the working principle and selection requirements of this method are introduced, and some common chemical probe systems for homogeneous and heterogeneous mixing processes are reviewed. The characteristics and applications of these systems are illustrated. Finally, the development of the new system is proposed.

关键词: mixing     chemical probe     liquid–liquid     heterogeneous    

Effect of lime on speciation of heavy metals during composting of water hyacinth

Jiwan SINGH,Ajay S. KALAMDHAD

《环境科学与工程前沿(英文)》 2016年 第10卷 第1期   页码 93-102 doi: 10.1007/s11783-014-0704-7

摘要: Composting is attractive and inexpensive method for treatment and biomass disposal of water hyacinth. However, the major disadvantage of water hyacinth composting is the high content of heavy metals in the final compost. Addition of lime sludge significantly reduced most bioavailable fractions (exchangeable and carbonate) of heavy metals. Studies were carried on composting of water hyacinth ( ) with cattle manure and sawdust (6:3:1 ratio) and effects of addition of lime (1%, 2% and 3%) on heavy metal speciation were evaluated during 30 days of composting period. The Tessier sequential extraction method was employed to investigate the changes in speciation of heavy metals such as Zinc (Zn), Copper (Cu), Manganese (Mn), Iron (Fe), Lead (Pb), Nickel (Ni), Cadmium (Cd) and Chromium (Cr) during water hyacinth composting. Effects of physicochemical parameters such as temperature, pH and organic matter on speciation of heavy metals were also studied during the process. Results showed that, the total metal content was increased during the composting process. The higher reduction in bioavailability factor (BF) of Cu, Fe, Ni, Cd and Cr was observed in lime 2 treatment about 62.1%, 64.4%, 71.9%, 62.1% and 58.9% respectively; however higher reduction in BF of Zn and Pb was observed in lime 1 treatment during the composting process. Reducible and oxidizable fractions of Ni, Pb and Cd were not observed during the process. Addition of lime was very effective for reduction of bioavailability of heavy metals during composting of water hyacinth with cattle manure and sawdust.

关键词: composting     lime     heavy metals     bioavailability factor     speciation    

Microfluidic production of liposomes through liquidliquid phase separation in ternary droplets

《化学科学与工程前沿(英文)》 2022年 第16卷 第6期   页码 1017-1022 doi: 10.1007/s11705-021-2118-y

摘要: Liposomes, the self-assembled phospholipid vesicles, have been extensively used in various fields such as artificial cells, drug delivery systems, biosensors and cosmetics. However, current microfluidic routes to liposomes mostly rely on water-in-oil-in-water double emulsion droplets as templates, and require complex fabrication of microfluidic devices, and tedious manipulation of multiphase fluids. Here we present a simple microfluidic approach to preparing monodisperse liposomes from oil-in-water droplets. For demonstration, we used butyl acetate-water-ethanol ternary mixtures as inner phase and an aqueous solution of surfactants as outer phase to make oil-in-water droplets, which can evolve into water-in-oil-in-water double emulsion droplets by liquid–liquid phase separation of ternary mixtures. Subsequently, the resultant water-in-oil-in-water droplets underwent a dewetting transition to form separated monodisperse liposomes and residual oil droplets, with the assistance of surfactants. The method is simple, does not require complex microfluidic devices and tedious manipulation, and provides a new platform for controllable preparation of liposomes.

关键词: microfluidics     liposomes     ternary droplets     phase separation    

Human health ambient water quality criteria for 13 heavy metals and health risk assessment in Taihu Lake

《环境科学与工程前沿(英文)》 2022年 第16卷 第4期 doi: 10.1007/s11783-021-1475-6

摘要:

• The concentrations of 13 heavy metals in Taihu Lake were analyzed.

关键词: Heavy metals     Human health ambient water quality criteria     Taihu Lake     Health risk assessment     Contribution rate    

Predicting non-carcinogenic hazard quotients of heavy metals in pepper (

Marzieh Mokarram, Hamid Reza Pourghasemi, Huichun Zhang

《环境科学与工程前沿(英文)》 2020年 第14卷 第6期 doi: 10.1007/s11783-020-1331-0

摘要: Abstract • There was significant absorption of heavy metals by the pepper in contaminated soils. • The target hazard quotient (THQ) indices followed the order of Pb>Zn>>Cd » Ni. • Relationships exist between contaminated plants and electromagnetic wave. • PCA and random search can select the main spectra and predict THQ for each element. Given the tendency of heavy metals to accumulate in soil and plants, the purpose of this study was to determine the contamination levels of Cd, Ni, Pb, and Zn on peppers (leaves and fruit) grown in contaminated soils in industrial centers. For this purpose, we measured the uptake of the four heavy metals by peppers grown in the heavy metal contaminated soils throughout the four growth stages: two-leaf, growth, flowering, and fruiting, and calculated various vegetation indices to evaluate the heavy metal contamination potentials. Electromagnetic waves were also applied for analyzing the responses of the target plants to various heavy metals. Based on the relevant spectral bands identified by principal component analysis (PCA) and random search methods, a regression method was then employed to determine the most optimal spectral bands for estimating the target hazard quotient (THQ). The THQ was found to be the highest in the plants contaminated by Pb (THQ= 62) and Zn (THQ= 5.07). The results of PCA and random search indicated that the spectra at the bands of b570, b650, and b760 for Pb, b400 and b1030 for Ni, b400 and b880 for Cd, and b560, b910, and b1050 for Zn were the most optimal spectra for assessing THQ. Therefore, in future studies, instead of examining the amount of heavy metals in plants by chemical analysis in the laboratory, the responses of the plants to the electromagnetic waves in the identified bands can be readily investigated in the field based on the established correlations.

关键词: Heavy metals     Plants     Target Hazard Quotient (THQ)     Principal Component Analysis (PCA)     Random search     Electromagnetic wave    

Re-evaluation of several heavy metals removal by natural limestones

Ali SDIRI,Samir BOUAZIZ

《化学科学与工程前沿(英文)》 2014年 第8卷 第4期   页码 418-432 doi: 10.1007/s11705-014-1455-5

摘要: Different treatment technologies have been efficiently applied to remove heavy metals from wastewater. Efforts have been made to find out the most economic water treatment technology by using low cost and easily accessible natural materials. On the other hand, heavy metals are the most threatening groundwater contaminants because of their toxicity and harmful effects on human and biota. This review discusses the use of natural geological materials for heavy metal removal in aqueous systems. Special attention has been devoted to natural limestone through a systematic inventory of relevant published reports. The removal of toxic metals may include different mechanisms (e.g., physisorption, chemisorptions, precipitation, etc.), depending on the physico-chemical properties of the material and the removed metal. Sorption of toxic metals (e.g., Pb, Cu, Cd, Zn, Cr, Hg, etc.) onto natural limestone involved precipitation of metal carbonate as a predominant removal process, but often subordinated by adsorption and ion exchange, depending on the physico-chemical properties of the studied limestone.

关键词: limestone     heavy metals     sorption     wastewater     passive treatment technology    

Energy distribution between liquid hydrogen and liquid oxygen temperatures in a Stirling/pulse tube refrigerator

《能源前沿(英文)》 2023年 第17卷 第4期   页码 516-526 doi: 10.1007/s11708-022-0844-6

摘要: A two-stage gas-coupled Stirling/pulse tube refrigerator (SPR), whose first and second stages respectively involve Stirling and pulse tube refrigeration cycles, is a very promising spaceborne refrigerator. The SPR has many advantages, such as a compact structure, high reliability, and high performance, and is expected to become an essential refrigerator for space applications. In research regarding gas-coupled regenerative refrigerator, the energy flow distribution between the two stages, and optimal phase difference between the pressure wave and volume flow, are two critical parameters that could widely influence refrigerator performance. The effects of displacer displacement on the pressure wave, phase difference, acoustic power distribution, and inter-stage cooling capacity shift of the SPR have been investigated experimentally. Notably, to obtain the maximum first-stage cooling capacity, an inflection point in displacement exists. When the displacer displacement is larger than the inflection point, the cooling capacity could be distributed between the first and second stages. In the present study, an SPR was designed and manufactured to work between the liquid hydrogen and liquid oxygen temperatures, which can be used to cool small-scale zero boil-off systems and space detectors. Under appropriate displacer displacement, the SPR can reach a no-load cooling temperature of 15.4 K and obtain 2.6 W cooling capacity at 70 K plus 0.1 W cooling capacity at 20 K with 160 W compressor input electric power.

关键词: Stirling/pulse tube refrigerator     displacer displacement     space application     phase shift     energy distribution    

Nanosized magnetite in low cost materials for remediation of water polluted with toxic metals, azo- and

María Fernanda HORST,Verónica LASSALLE,María Luján FERREIRA

《环境科学与工程前沿(英文)》 2015年 第9卷 第5期   页码 746-769 doi: 10.1007/s11783-015-0814-x

摘要: Nanosized magnetite has emerged as an adsorbent of pollutants in water remediation. Nanoadsorbents include magnetic iron oxide and its modifiers/stabilizers, such as carbon, silica, clay, organic moieties (polymers, aminoacids, and fatty acids) and other inorganic oxides. This review is focused on the recent developments on the synthesis and use of magnetic nanoparticles and nanocomposites in the treatment of contaminated water. The emphasis is on the influence of the iron oxide modifiers on some properties of interest such as size, BET area, and magnetization. The characteristics of these nanomaterials are related to their ability to eliminate heavy metal ions and dyes from wastewater. Comparative analysis of the actual literature was performed aiming to present the magnetic material, its preparation methodology and performance in the elimination of the selected pollutants. Vast information has been properly summarized according to the materials, their properties and preferential affinity for selected contaminants. The mechanisms governing nanomaterial’s formation as well as the interactions with heavy metals and dyes have been carefully analyzed and associated to their efficiency.

关键词: nanomagnetite     water remediation     toxic metals     dyes     supported magnetite    

Non-toxic, high selectivity process for the extraction of precious metals from waste printed circuit

《环境科学与工程前沿(英文)》 2023年 第17卷 第10期 doi: 10.1007/s11783-023-1723-z

摘要:

● Au, Ag and Pd were recovered from WPCBs with high efficiencies.

关键词: Thiosulfate     Printed circuit boards     Precious metals     Leaching     Hydrometallurgy    

标题 作者 时间 类型 操作

Emerging roles of liquid metals in carbon neutrality

期刊论文

Revolutionizing heat transport enhancement with liquid metals: Proposal of a new industry of water-free

Haiyan LI, Jing LIU

期刊论文

Unconventional hydrodynamics of hybrid fluid made of liquid metals and aqueous solution under applied

Xu-Dong ZHANG, Yue SUN, Sen CHEN, Jing LIU

期刊论文

Perspective on gallium-based room temperature liquid metal batteries

期刊论文

Liquid-based high-temperature receiver technologies for next-generation concentrating solar power: A

期刊论文

ASSESSMENT OF HEAVY METALS IN HYDROCHAR PRODUCED BY HYDROTHERMAL CARBONIZATION OF DAIRY MANURE

期刊论文

Chemical probe systems for assessing liquidliquid mixing efficiencies of reactors

期刊论文

Effect of lime on speciation of heavy metals during composting of water hyacinth

Jiwan SINGH,Ajay S. KALAMDHAD

期刊论文

Microfluidic production of liposomes through liquidliquid phase separation in ternary droplets

期刊论文

Human health ambient water quality criteria for 13 heavy metals and health risk assessment in Taihu Lake

期刊论文

Predicting non-carcinogenic hazard quotients of heavy metals in pepper (

Marzieh Mokarram, Hamid Reza Pourghasemi, Huichun Zhang

期刊论文

Re-evaluation of several heavy metals removal by natural limestones

Ali SDIRI,Samir BOUAZIZ

期刊论文

Energy distribution between liquid hydrogen and liquid oxygen temperatures in a Stirling/pulse tube refrigerator

期刊论文

Nanosized magnetite in low cost materials for remediation of water polluted with toxic metals, azo- and

María Fernanda HORST,Verónica LASSALLE,María Luján FERREIRA

期刊论文

Non-toxic, high selectivity process for the extraction of precious metals from waste printed circuit

期刊论文